A beautiful pattern in bilayer graphene

A beautiful pattern in bilayer graphene

A curious measurement

At the Kirchberg conference, the experimentalists from ETH Zürich came to us with transconductance measurements of electrostatically defined quantum point contacts in bilayer graphene. The fan diagrams showed a striking interweaving pattern: fourfold (spin+valley) degenerate modes at zero magnetic field split into twofold (by valley) at intermediate fields, then restore fourfold degeneracy in the quantum Hall regime. During that transition, levels from one valley shift by exactly two in quantum number relative to the other. The pattern was robust across different QPCs, channel widths, and displacement fields. Why? Or was the "two" a coincidence?

Numerical Calculation

We could quickly reproduce the pattern numerically by sweeping the magnetic field in a tight-binding eigenvalue computation of the states in the ribbon. The two limiting cases are even solvable by hand: At B=0B = 0 we have valley degenerate size-quantized modes and at high BB we see Landau levels.

Differential conductance dG/dE of a
  180 nm wide BLG nanoribbon, including a thermal
  smoothening of 1.7 K. b) and c) show separately the contributions
  from the two valleys K+ and K- at low energies. 
  The channel voltage is determined through the V to E relation. Reproduced with permission from Overweg et al., Phys. Rev. Lett. 121, 257702 (2018). © 2018 American Physical Society.
Differential conductance dG/dE of a 180 nm wide BLG nanoribbon, including a thermal smoothening of 1.7 K. b) and c) show separately the contributions from the two valleys K+ and K- at low energies. The channel voltage is determined through the V to E relation. Reproduced with permission from Overweg et al., Phys. Rev. Lett. 121, 257702 (2018). © 2018 American Physical Society.

The answer is already visible in the effective low-energy Hamiltonian of bilayer graphene. In a perpendicular magnetic field it reads

H2,ξ=12mλB2(0(ξy~ipy~)2(ξy~+ipy~)20)\mathcal{H}_{2,\xi} = -\frac{1}{2m\lambda_B^2} \begin{pmatrix} 0 & (\xi \tilde{y} - i p_{\tilde{y}})^2 \\ (\xi \tilde{y} + i p_{\tilde{y}})^2 & 0 \end{pmatrix}

where λB=c/(eB)\lambda_B = \sqrt{\hbar c/(eB)} is the magnetic length, m=γ1/(2v2)m = \gamma_1/(2v^2), and ξ=±1\xi = \pm 1 is the valley index. The key object is the operator π=y~+ipy~\pi = \tilde{y} + ip_{\tilde{y}}, which in a magnetic field becomes proportional to the harmonic oscillator lowering operator aa. The off-diagonal blocks contain π2\pi^2 — this squared structure, specific to bilayer graphene, is a winding number J=2J = 2.

What are the zero-energy eigenstates of this Hamiltonian? They must satisfy π2ψ=0\pi^2|\psi\rangle = 0, i.e., a2ψ=0a^2|\psi\rangle = 0. There are exactly two such states — the harmonic oscillator ground state ϕ0\phi_0 and first excited state ϕ1\phi_1. These two zero modes live entirely on one sublattice. When a displacement field is applied, that sublattice polarization pins them to one layer, and they appear only in one valley's conduction band (say K+K_+ for B>0B > 0). All higher Landau levels N2N \geq 2 appear in both valleys.

This asymmetry dictates what must happen during the adiabatic transition from zero field to high field. At B=0B = 0, both valleys have the same size-quantized states: n=1,2,3,n = 1, 2, 3, \ldots At high BB, valley K+K_+ has Landau levels N=0,1,2,3,N = 0, 1, 2, 3, \ldots in the conduction band, while KK_- has only N=2,3,4,N = 2, 3, 4, \ldots — it is missing two states. Since the evolution is smooth and levels cannot appear or disappear, the only consistent mapping is that KK_- levels must shift up by two: the size-quantized state nKn_{K_-} evolves into Landau level (n+2)K(n+2)_{K_-}. This is the interweaving pattern we observe.

Topological Invariants

This is actually an index theorem at work. The number "two" is the index of the operator π2\pi^2. In general, the index of an operator DD is defined as

ind(D)=dimker(D)dimker(D)\mathrm{ind}(D) = \dim\ker(D) - \dim\ker(D^\dagger)

— the number of zero modes of DD minus the number of zero modes of DD^\dagger. For our operator π2\pi^2: the kernel has dimension two (the states ϕ0,ϕ1\phi_0, \phi_1), while the kernel of (π)2(\pi^\dagger)^2 is empty (there are no normalizable solutions). So ind(π2)=2\mathrm{ind}(\pi^2) = 2.

The index cannot change under continuous deformations of the operator. So changing the channel width, the displacement field, the shape of the confinement potential - these don't appear in π\pi.

The adiabatic transition between the two regimes is an instance of spectral flow: as the magnetic field is turned on, eigenvalues move continuously, and the net number of states that "flow" from one part of the spectrum to another is fixed by the index. The spectral flow equals the index equals the winding number.

Generalization

This was all a single-valley calculation. The full lattice Hamiltonian contains both K+K_+ and KK_- with opposite winding (+2+2 and 2-2), and the total index is zero — as guaranteed by the Nielsen-Ninomiya theorem. So why do we observe the clean single-valley topology and not a mix? Because inter-valley scattering requires momentum transfer on the order of the inverse lattice constant.

The generalization is: For monolayer graphene the Hamiltonian has π1\pi^1 in the off-diagonal — winding J=1J = 1. There is one zero mode, and the shift between valleys during the adiabatic transition is one. While the smooth confinement for single-layer graphene is hard to achieve experimentally, we confirmed this numerically. For ABC-stacked trilayer graphene, J=3J = 3, the prediction is three zero modes and a shift by three.

Read the paper Topologically nontrivial valley states in bilayer graphene quantum point contacts by Hiske Overweg, Angelika Knothe, Thomas Fabian, Lukas Linhart, Peter Rickhaus, Lucien Wernli, Kenji Watanabe, Takashi Taniguchi, David Sánchez, Joachim Burgdörfer, Florian Libisch, Vladimir I Fal’ko, Klaus Ensslin, Thomas Ihn; Phys. Rev. Lett. 121, 257702 (2018) here or on arxiv.